Crystal structure of dibenzoyl diselenide.
نویسندگان
چکیده
C14H10O2Se2 is monoclinic, P2(1)/c. The unit-cell dimensions at 293 K are a = 12.795(2), b = 12.126(2), c = 9.0179(13)A, beta = 107.074(6)degrees, V = 1337.5(3)A3, and Z = 4. The R value is 0.048 for 2319 observed reflections. The dihedral angle between the plane C4-C7(O2)-Se1 and C9-C8(O1)-Se2 is 85.6(2)degrees, keeping the Se atom unshared electron pairs in a more stable configuration with the rest of the molecule. The packing in the crystal is entirely due to van der Waals forces.
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ورودعنوان ژورنال:
- Analytical sciences : the international journal of the Japan Society for Analytical Chemistry
دوره 19 6 شماره
صفحات -
تاریخ انتشار 2003